Niue, a pacific island nation just east of Tonga, holds a little over 2000 people. According to the CIA world factbook, an important source of revenue for Niue is "the sale of postage stamps to foreign collectors."
lib.utexas.edu/maps/australia...
cia.gov/cia/publicatio...
Niue has only one ISP, but gets its own ccTLD, ".nu".
Glenn Fleishman has made a really neat-looking book searching site that, while hosted in what seems to be Seattle, has a .nu TLD in "an attempt to show how smarter systems combined with cleaner URLs can create shortcuts around roadblocks." (Much like this site, except for the shortcut-around-roadblocks part.)
isbn.nu/ - (thanks, Krista.)